The rod-like N3– ion forms a water stable inclusion complex with a tris-imidazolium cage containing a FeII(bpy)32+ subunit as a cap, and establishes multipoint H bond interactions with the C–H fragments offered by the receptor. The N3– complex is 80-fold more stable than that formed by the spherical Cl– ion, which receives 6 H bonds from 6 C–H fragments.

A metal-based trisimidazolium cage that provides six C-H hydrogen-bond-donor fragments and includes anions

AMENDOLA, VALERIA;BOIOCCHI, MASSIMO;COLASSON, BENOIT XAVIER;FABBRIZZI, LUIGI;
2006-01-01

Abstract

The rod-like N3– ion forms a water stable inclusion complex with a tris-imidazolium cage containing a FeII(bpy)32+ subunit as a cap, and establishes multipoint H bond interactions with the C–H fragments offered by the receptor. The N3– complex is 80-fold more stable than that formed by the spherical Cl– ion, which receives 6 H bonds from 6 C–H fragments.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/143384
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 111
  • ???jsp.display-item.citation.isi??? 107
social impact