Insummary, using the readily available [ReOCl3(OPPh3)DMS)] complex we have developed a new general catalytic procedure for the rapid and efficient 1,3-rearrangement of free secondary alcohols to the corresponding alpha-beta usatured carbonyl compounds with virtually complete E stereoselectivity.

A simple and versatile Re-catalyzed Meyer-Schuster rearrangement of propargylic alcohols to α,β-unsaturated carbonyl compounds

LUPARIA, MARCO;PORTA, ALESSIO;ZANONI, GIUSEPPE
Conceptualization
;
VIDARI, GIOVANNI
2009-01-01

Abstract

Insummary, using the readily available [ReOCl3(OPPh3)DMS)] complex we have developed a new general catalytic procedure for the rapid and efficient 1,3-rearrangement of free secondary alcohols to the corresponding alpha-beta usatured carbonyl compounds with virtually complete E stereoselectivity.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/148380
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