Insummary, using the readily available [ReOCl3(OPPh3)DMS)] complex we have developed a new general catalytic procedure for the rapid and efficient 1,3-rearrangement of free secondary alcohols to the corresponding alpha-beta usatured carbonyl compounds with virtually complete E stereoselectivity.
A simple and versatile Re-catalyzed Meyer-Schuster rearrangement of propargylic alcohols to α,β-unsaturated carbonyl compounds
LUPARIA, MARCO;PORTA, ALESSIO;ZANONI, GIUSEPPEConceptualization
;VIDARI, GIOVANNI
2009-01-01
Abstract
Insummary, using the readily available [ReOCl3(OPPh3)DMS)] complex we have developed a new general catalytic procedure for the rapid and efficient 1,3-rearrangement of free secondary alcohols to the corresponding alpha-beta usatured carbonyl compounds with virtually complete E stereoselectivity.File in questo prodotto:
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