The heats and entropies of fusion and the heats of crystn. of Cr(CO)6, Mo(CO)6, and W(CO)6 were detd. in sealed, evacuated glass ampuls by differential scanning calorimetry. The values were combined with published sublimation data to calc. the heats of vaporization (ΔHv). The solid-gas and liq.-gas phase diagrams were detd. from ΔHv and the reported heats of sublimation, and gave the b.ps. of the 3 compds.
Melting of Group VI transition metal hexacarbonyls: thermodynamic parameters
FABBRIZZI, LUIGI;
1976-01-01
Abstract
The heats and entropies of fusion and the heats of crystn. of Cr(CO)6, Mo(CO)6, and W(CO)6 were detd. in sealed, evacuated glass ampuls by differential scanning calorimetry. The values were combined with published sublimation data to calc. the heats of vaporization (ΔHv). The solid-gas and liq.-gas phase diagrams were detd. from ΔHv and the reported heats of sublimation, and gave the b.ps. of the 3 compds.File in questo prodotto:
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