By gamma irradiation of cycloheptatriene, bicyclo(3.3.0)octene and dehydrodicyclopentadiene in chlorofluorocarbon matrices at 77 K the radical cations generated by electron loss from the parent molecules have been obtained and their electronic structure analyzed by EPR spectroscopy and by INDO and MNDO-PM3 molecular orbital calculations. On warming above 77 K these species undergo deprotonation to form neutral radicals. In the case of dicyclopentadiene the primary radical-cation is not stable at 77 K but decomposes probably by ring opening giving a bis-allylilic type cation-radical.

EPR study of cation-radicals of cyclic alkenes in chlorofluorocarbon matrices

FAUCITANO, ANTONIO;BUTTAFAVA, ARMANDO;MARTINOTTI, FAUSTA
1995-01-01

Abstract

By gamma irradiation of cycloheptatriene, bicyclo(3.3.0)octene and dehydrodicyclopentadiene in chlorofluorocarbon matrices at 77 K the radical cations generated by electron loss from the parent molecules have been obtained and their electronic structure analyzed by EPR spectroscopy and by INDO and MNDO-PM3 molecular orbital calculations. On warming above 77 K these species undergo deprotonation to form neutral radicals. In the case of dicyclopentadiene the primary radical-cation is not stable at 77 K but decomposes probably by ring opening giving a bis-allylilic type cation-radical.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/465324
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