We study a class of quadratic Hamiltonians which describe both fully attractive and partly repulsive molecular interactions, characteristic of biaxial liquid crystal molecules. To treat the partly repulsive interactions we establish a minimax principle for the associated mean-field free energy. We show that the phase diagram described by Sonnet et al. [Phys. Rev. E 67, 061701 (2003)] is universal. Our predictions are in good agreement with the recent observations on both V-shaped and tetrapodal molecules.

Universal mean-field phase diagram for biaxial nematics obtained from a minimax principle

BISI, FULVIO;VIRGA, EPIFANIO GUIDO GIOVANNI;DE MATTEIS, GIOVANNI;
2006-01-01

Abstract

We study a class of quadratic Hamiltonians which describe both fully attractive and partly repulsive molecular interactions, characteristic of biaxial liquid crystal molecules. To treat the partly repulsive interactions we establish a minimax principle for the associated mean-field free energy. We show that the phase diagram described by Sonnet et al. [Phys. Rev. E 67, 061701 (2003)] is universal. Our predictions are in good agreement with the recent observations on both V-shaped and tetrapodal molecules.
2006
The Mathematics category includes resources dealing with mathematics, applied mathematics, statistics and probability.
Esperti anonimi
Inglese
Internazionale
STAMPA
73
051709
Nematic liquid crystals; minmax principle; biaxiality
http://scitation.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=PLEEE8000073000005051709000001&idtype=cvips&gifs=yes
6
info:eu-repo/semantics/article
262
Bisi, Fulvio; Virga, EPIFANIO GUIDO GIOVANNI; E. C., GARTLAND JR; DE MATTEIS, Giovanni; A. M., Sonnet; G. E., Durand
1 Contributo su Rivista::1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/103769
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