Fully attractive and partly repulsive molecular interactions, characteristic of biaxial liquid crystal molecules, are described by a class of quadratic Hamiltonians, originally put forward by Straley. The partly repulsive interactions require a minimax principle for the associated mean-field free energy. By analyzing the different phases in a bifurcation scenario, we show that the phase diagram described by Sonnet et al. [Phys. Rev. E 67 061701 (2003)] is universal. Our model predictions are in agreement with recent observations on both V-shaped and tetrapodal molecules.

Universal mean-field phase diagram for biaxial nematics

BISI, FULVIO
2008-01-01

Abstract

Fully attractive and partly repulsive molecular interactions, characteristic of biaxial liquid crystal molecules, are described by a class of quadratic Hamiltonians, originally put forward by Straley. The partly repulsive interactions require a minimax principle for the associated mean-field free energy. By analyzing the different phases in a bifurcation scenario, we show that the phase diagram described by Sonnet et al. [Phys. Rev. E 67 061701 (2003)] is universal. Our model predictions are in agreement with recent observations on both V-shaped and tetrapodal molecules.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/103776
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