Fully attractive and partly repulsive molecular interactions, characteristic of biaxial liquid crystal molecules, are described by a class of quadratic Hamiltonians, originally put forward by Straley. The partly repulsive interactions require a minimax principle for the associated mean-field free energy. By analyzing the different phases in a bifurcation scenario, we show that the phase diagram described by Sonnet et al. [Phys. Rev. E 67 061701 (2003)] is universal. Our model predictions are in agreement with recent observations on both V-shaped and tetrapodal molecules.

Universal mean-field phase diagram for biaxial nematics

BISI, FULVIO
2008-01-01

Abstract

Fully attractive and partly repulsive molecular interactions, characteristic of biaxial liquid crystal molecules, are described by a class of quadratic Hamiltonians, originally put forward by Straley. The partly repulsive interactions require a minimax principle for the associated mean-field free energy. By analyzing the different phases in a bifurcation scenario, we show that the phase diagram described by Sonnet et al. [Phys. Rev. E 67 061701 (2003)] is universal. Our model predictions are in agreement with recent observations on both V-shaped and tetrapodal molecules.
2008
The Mathematics category includes resources dealing with mathematics, applied mathematics, statistics and probability.
Esperti anonimi
Inglese
Internazionale
STAMPA
480
182
201
20
NEMATIC LIQUID CRYSTALS; BIAXIALITY; MINIMAX PRINCIPLE
http://www.informaworld.com/smpp/content~content=a790749504~db=all~order=page
no
1
info:eu-repo/semantics/article
262
Bisi, Fulvio
1 Contributo su Rivista::1.1 Articolo in rivista
none
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/103776
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