On the origin of some red soils from Sardinia (Italy): a neutron activation analysis investigation

In Sardinia, the Italian island in the middle of the Mediterranean Sea, there are many red soils developed on limestone or dolomite. Soil and underlying bedrock samples from 5 different sites have been submitted to chemical and mineralogical characterization, by using standard X-ray diffraction analysis, spectrochemical methods and instrumental neutron activation analysis. Obtained results are presented and discussed in terms of precision and accuracy. Trace element concentration variation with depth is discussed as well as the enrichment/depletion ratios between soils and rocks, and the rare-earth element distribution. Data analysis suggests for some soils a formation process based on the evolution of the underlying bedrock, and for the other soils a formation process partly based on the evolution of the local rock but with meaningful contributions of external sources, both eolian and/or alluvial.