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Irradiation of the 6,8-difluoroquinolone antibiotic lomefloxacin causes selective heterolytic defluorination from position 8 and leads to products rationalized as arising from the cation either via nucleophile addition or intramolecular carbene C–H insertion and hydrogen transfer.

The photochemistry of lomefloxacin. An aromatic carbene as the key intermediate in both photodecomposition and photocarcinogenesis

FASANI, ELISA;MELLA, MARIELLA;FAGNONI, MAURIZIO;ALBINI, ANGELO
1997-01-01

Abstract

Irradiation of the 6,8-difluoroquinolone antibiotic lomefloxacin causes selective heterolytic defluorination from position 8 and leads to products rationalized as arising from the cation either via nucleophile addition or intramolecular carbene C–H insertion and hydrogen transfer.
1997
The Chemistry category includes resources that are general in nature and cover a broad spectrum of topics in the chemical sciences. Resources specifically covering analytical chemistry, inorganic and nuclear chemistry, organic chemistry, physical chemistry, and polymer science will be placed in those particular categories. Miscellaneous and applied chemistry resources may be placed in this category when not appropriate for specific subfields in chemistry.
CHEMICAL COMMUNICATIONS
sì
Sì, ma tipo non specificato
Inglese
Internazionale
ELETTRONICO
1329
1330
2
photochemistry; lomefloxacin. carbene
6
info:eu-repo/semantics/article
262
Fasani, Elisa; Mella, Mariella; Caccia, D.; Tassi, S.; Fagnoni, Maurizio; Albini, Angelo
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/106900
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