The binding tendencies toward carboxylates of a trifurcated receptor containing three copper(II)−cyclam subunits have been investigated in pure water, through the displacement of a fluorescent indicator. The receptor is tailor-made for the recognition of tricarboxylates, e.g., citrate, whose three negatively charged oxygen atoms interact with the three coordinatively unsaturated CuII centers.
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Titolo: | Metal-Containing Trifurcate Receptor that Recognizes and Senses Citrate in Water |
Autori: | |
Data di pubblicazione: | 2005 |
Rivista: | |
Abstract: | The binding tendencies toward carboxylates of a trifurcated receptor containing three copper(II)−cyclam subunits have been investigated in pure water, through the displacement of a fluorescent indicator. The receptor is tailor-made for the recognition of tricarboxylates, e.g., citrate, whose three negatively charged oxygen atoms interact with the three coordinatively unsaturated CuII centers. |
Handle: | http://hdl.handle.net/11571/107252 |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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