CONTENTS 1. Introduction 9922 2. Epoxidation Reactions 9925 3. Cyclopropanation Reactions 9929 4. Michael Reactions 9930 4.1. Aza-Michael Reactions 9945 4.2. Sulfa-Michael Reactions 9949 4.3. Phospha-Michael Reactions 9951 5. Radical Reactions 9953 6. Diels−Alder Reactions 9956 7. 1,3-Dipolar and Formal [3+2] Cycloaddition Reactions 9959 8. Influence of Substituents on Reactivity and Selectivity 9964 9. Comparison between Catalytic, Enantioselective Reactions with Different 1-(Nitrogen-heterocyclic)- Substituted Prop-2-en-1-ones 1−9 and the Aromatic Analogues 10 9968 10. Relationship between Different [Chiral Ligand/ Inorganic Cation] Complexes or Non-Racemic Organocatalysts and the Stereochemical Outcome 9969 11. Conclusions 9976
Enantioselective Catalytic Reactions with N-Acyliden Penta-atomic Aza-heterocycles. Heterocycles as Masked Bricks To Build Chiral Scaffolds
DESIMONI, GIOVANNI
Writing – Original Draft Preparation
;FAITA, GIUSEPPEFormal Analysis
;QUADRELLI, PAOLOFormal Analysis
2015-01-01
Abstract
CONTENTS 1. Introduction 9922 2. Epoxidation Reactions 9925 3. Cyclopropanation Reactions 9929 4. Michael Reactions 9930 4.1. Aza-Michael Reactions 9945 4.2. Sulfa-Michael Reactions 9949 4.3. Phospha-Michael Reactions 9951 5. Radical Reactions 9953 6. Diels−Alder Reactions 9956 7. 1,3-Dipolar and Formal [3+2] Cycloaddition Reactions 9959 8. Influence of Substituents on Reactivity and Selectivity 9964 9. Comparison between Catalytic, Enantioselective Reactions with Different 1-(Nitrogen-heterocyclic)- Substituted Prop-2-en-1-ones 1−9 and the Aromatic Analogues 10 9968 10. Relationship between Different [Chiral Ligand/ Inorganic Cation] Complexes or Non-Racemic Organocatalysts and the Stereochemical Outcome 9969 11. Conclusions 9976I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
