β- or γ-Site-selective C-H alkylation of aliphatic nitriles has been achieved using a decatungstate salt as the photocatalyst. The observed site selectivity was justified by a radical polar effect in transition states for hydrogen abstraction.
Photocatalyzed Site-selective C-H to C-C Conversion of Aliphatic Nitriles
RAVELLI, DAVIDE;FAGNONI, MAURIZIO;
2015-01-01
Abstract
β- or γ-Site-selective C-H alkylation of aliphatic nitriles has been achieved using a decatungstate salt as the photocatalyst. The observed site selectivity was justified by a radical polar effect in transition states for hydrogen abstraction.File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
DRAFT OL.pdf
accesso aperto
Tipologia:
Documento in Pre-print
Licenza:
Creative commons
Dimensione
327.94 kB
Formato
Adobe PDF
|
327.94 kB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
