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Using copper(II) chiral complexes as catalysts, enantioselective Michael reactions were performed. The degree of enantioselectivity depended on the design of the catalyst and the best results (70% e.e.) were obtained with tetradentate ligands.

Copper(II) in organic synthesis. VIII enantioselective michael reactions with chiral copper(II) complexes as catalysts

DESIMONI, GIOVANNI;QUADRELLI, PAOLO;RIGHETTI, PIER PAOLO
1990-01-01

Abstract

Using copper(II) chiral complexes as catalysts, enantioselective Michael reactions were performed. The degree of enantioselectivity depended on the design of the catalyst and the best results (70% e.e.) were obtained with tetradentate ligands.
1990
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
TETRAHEDRON
sì
A1990DC34300025
2-s2.0-0001236767
Esperti anonimi
Inglese
Internazionale
STAMPA
46
8
2927
2934
8
Biochemistry; Drug Discovery3003 Pharmaceutical Science; Organic Chemistry
no
3
info:eu-repo/semantics/article
262
Desimoni, Giovanni; Quadrelli, Paolo; Righetti, PIER PAOLO
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/1154702
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