Non-classical (bridging) and classical (Woodward-Hoffmann) secondary orbital interactions as well as a favourable electrostatic interaction are involved in the stabilization of the two lowest transition passes of the acrolein dimerization. The heteroatoms provide anchimeric assistance to the hetero Diels-Alder reaction through a neighbouring-group mechanism.
Classical and non-classical secondary orbital interactions and Coulombic attraction in regiospecific dimerization of acrolein
TOMA, LUCIO;QUADRELLI, PAOLO;CARAMELLA, PIERLUIGI
2001-01-01
Abstract
Non-classical (bridging) and classical (Woodward-Hoffmann) secondary orbital interactions as well as a favourable electrostatic interaction are involved in the stabilization of the two lowest transition passes of the acrolein dimerization. The heteroatoms provide anchimeric assistance to the hetero Diels-Alder reaction through a neighbouring-group mechanism.File in questo prodotto:
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