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1,2,4-Oxadiazole-4-oxides undergo clean thermal cleavage in refluxing chlorobenzene or xylene to nitriles and nitrosocarbonyl intermediates, which are either trapped with suitable olefins to afford ene adducts or dimerize and rearrange to anhydrides.

A thermal fragmentation of 1,2,4-oxadiazole-4-oxides to nitriles and nitrosocarbonyls

QUADRELLI, PAOLO;MELLA, MARIELLA;CARAMELLA, PIERLUIGI
2000-01-01

Abstract

1,2,4-Oxadiazole-4-oxides undergo clean thermal cleavage in refluxing chlorobenzene or xylene to nitriles and nitrosocarbonyl intermediates, which are either trapped with suitable olefins to afford ene adducts or dimerize and rearrange to anhydrides.
2000
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TETRAHEDRON LETTERS
sì
000086086100038
2-s2.0-0034681733
Sì, ma tipo non specificato
Inglese
Internazionale
STAMPA
41
2019
2022
4
ene reactions; nitroso compounds; 1; 2; 4-OXADIAZOLE-4-OXIDES; FRAGMENTATION
4
info:eu-repo/semantics/article
262
Quadrelli, Paolo; Campari, Gigliola; Mella, Mariella; Caramella, Pierluigi
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/116005
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