Nitrosocarbonyl intermediates, generated at r.t. by the mild oxidation of nitrile oxides, undergo clean ene reactions with tetramethyl- and trimethyl-ethylene and with cyclohexene. With less substituted ethylenes the ene pathway is still active but the oxidation step of the nitrile oxides competes with the cycloadditions to the olefins.
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Titolo: | Nitrosocarbonyl Intermediates as Super-Enophiles: a Mild Method for Carbon-Nitrogen Bond Formation |
Autori: | |
Data di pubblicazione: | 1998 |
Rivista: | |
Abstract: | Nitrosocarbonyl intermediates, generated at r.t. by the mild oxidation of nitrile oxides, undergo clean ene reactions with tetramethyl- and trimethyl-ethylene and with cyclohexene. With less substituted ethylenes the ene pathway is still active but the oxidation step of the nitrile oxides competes with the cycloadditions to the olefins. |
Handle: | http://hdl.handle.net/11571/116066 |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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