For the first time, the tetrafluorobenzyl unit has been considered as a C–H⋯anion binding motif. In synergy with imidazolium groups within a bowl-shaped receptor, it has allowed for the effective binding of chloride in solution. Remarkable affinity was observed in organic–water mixtures.
Chloride-binding in organic–water mixtures: the powerful synergy of C–H donor groups within a bowl-shaped cavity
AMENDOLA, VALERIA
Project Administration
;BERGAMASCHI, GRETA;BOIOCCHI, MASSIMO;LEGNANI, LAURA;MILJKOVIC, ANA;MONZANI, ENRICO;
2016-01-01
Abstract
For the first time, the tetrafluorobenzyl unit has been considered as a C–H⋯anion binding motif. In synergy with imidazolium groups within a bowl-shaped receptor, it has allowed for the effective binding of chloride in solution. Remarkable affinity was observed in organic–water mixtures.File in questo prodotto:
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