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Li6C60 has been cho­sen as the most rep­re­sen­ta­tive sys­tem to study the hy­dro­gena­tion mech­a­nism in al­kali-clus­ter in­ter­ca­lated ful­lerides. We pre­sent here a muon spin re­lax­ation (μSR) ex­per­i­ment that hints the chance to achieve a higher stor­age ca­pac­ity on fullerene with re­spect to the val­ues sug­gested in lit­er­a­ture. More­over, a lin­ear re­la­tion­ship be­tween the muo­nium adduct rad­i­cal hy­per­fine fre­quency and the level of C60 hy­dro­gena­tion was found and it can be ex­ploited to probe the C60 hy­dro­gena­tion level, giv­ing more credit to this tech­nique in the field of hy­dro­gen stor­age ma­te­ri­als.

Extending the hydrogen storage limit in fullerene

Milanese, Chiara
Investigation
;
2017-01-01

Abstract

Li6C60 has been cho­sen as the most rep­re­sen­ta­tive sys­tem to study the hy­dro­gena­tion mech­a­nism in al­kali-clus­ter in­ter­ca­lated ful­lerides. We pre­sent here a muon spin re­lax­ation (μSR) ex­per­i­ment that hints the chance to achieve a higher stor­age ca­pac­ity on fullerene with re­spect to the val­ues sug­gested in lit­er­a­ture. More­over, a lin­ear re­la­tion­ship be­tween the muo­nium adduct rad­i­cal hy­per­fine fre­quency and the level of C60 hy­dro­gena­tion was found and it can be ex­ploited to probe the C60 hy­dro­gena­tion level, giv­ing more credit to this tech­nique in the field of hy­dro­gen stor­age ma­te­ri­als.
2017
Materials Science and Engineering is concerned with admixtures of matter or the basic matter from which products are made. The category covers ceramics, paper and wood products, polymers, textiles, composites, coatings & films, and biomaterials. Other areas covered in this category include Materials Chemistry, the application of chemistry to materials design and testing; Condensed Matter/Solid State Physics, the branch of physics concerned with the structure and properties of condensed matter (superconductors, semiconductors, ferroelectrics, and dielectrics); and Physical Chemistry/Chemical Physics, the application of the concepts and laws of physics to chemical phenomena.
The Physical Chemistry/Chemical Physics category includes resources on photochemistry, solid state chemistry, kinetics, catalysis, quantum chemistry, surface chemistry, electro-chemistry, chemical thermodynamics, thermo-physics, colloids, fullerenes and zeolites. Resources dealing with (liquid) crystals and crystallography are also included in this category. This category also includes resources on atomic, molecular and chemical physics, which concerns the structure of atoms and molecules, atomic and molecular interactions with radiation, magnetic resonance and relaxation, Mossbauer effect, and atomic and molecular collision processes and interactions.
CARBON
sì
WOS:000403665000010
2-s2.0-85019154593
Esperti anonimi
Inglese
Internazionale
ELETTRONICO
120
77
82
6
fullerene, Li fullerides, hydrogen storage, muon spin re­lax­ation (μSR)
sì
8
info:eu-repo/semantics/article
262
Gaboardi, M.; Sarzi, Amadè; Aramini, M.; Milanese, Chiara; Magnani, G.; Sanna, Samuele; Riccò, M.; Pontiroli, D.
1 Contributo su Rivista::1.1 Articolo in rivista
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1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/1180873
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