The Ca(BH4)(2)-Mg2NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4)(2)-based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5B2 is formed upon dehydrogenation and the formation of Ca(BH4)(2) upon rehydrogenation is confirmed.
Ca(BH4)(2)-Mg2NiH4: on the pathway to a Ca(BH4)(2) system with a reversible hydrogen cycle
MILANESE, CHIARAInvestigation
;
2016-01-01
Abstract
The Ca(BH4)(2)-Mg2NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4)(2)-based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5B2 is formed upon dehydrogenation and the formation of Ca(BH4)(2) upon rehydrogenation is confirmed.File in questo prodotto:
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