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The Ca(BH4)(2)-Mg2NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4)(2)-based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5B2 is formed upon dehydrogenation and the formation of Ca(BH4)(2) upon rehydrogenation is confirmed.

Ca(BH4)(2)-Mg2NiH4: on the pathway to a Ca(BH4)(2) system with a reversible hydrogen cycle

MILANESE, CHIARA
Investigation
;
2016-01-01

Abstract

The Ca(BH4)(2)-Mg2NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4)(2)-based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5B2 is formed upon dehydrogenation and the formation of Ca(BH4)(2) upon rehydrogenation is confirmed.
2016
Materials Science and Engineering is concerned with admixtures of matter or the basic matter from which products are made. The category covers ceramics, paper and wood products, polymers, textiles, composites, coatings & films, and biomaterials. Other areas covered in this category include Materials Chemistry, the application of chemistry to materials design and testing; Condensed Matter/Solid State Physics, the branch of physics concerned with the structure and properties of condensed matter (superconductors, semiconductors, ferroelectrics, and dielectrics); and Physical Chemistry/Chemical Physics, the application of the concepts and laws of physics to chemical phenomena.
The Physical Chemistry/Chemical Physics category includes resources on photochemistry, solid state chemistry, kinetics, catalysis, quantum chemistry, surface chemistry, electro-chemistry, chemical thermodynamics, thermo-physics, colloids, fullerenes and zeolites. Resources dealing with (liquid) crystals and crystallography are also included in this category. This category also includes resources on atomic, molecular and chemical physics, which concerns the structure of atoms and molecules, atomic and molecular interactions with radiation, magnetic resonance and relaxation, Mossbauer effect, and atomic and molecular collision processes and interactions.
CHEMICAL COMMUNICATIONS
sì
WOS:000372662100024
2-s2.0-84962092463
Esperti anonimi
Inglese
Internazionale
ELETTRONICO
52
26
4836
4839
4
hydrogen storage, SORPTION PROPERTIES; HYDRIDE COMPOSITES; DECOMPOSITION; BOROHYDRIDES; MG2NIH4, Ca borohydride
sì
9
info:eu-repo/semantics/article
262
Bergemann, N; Pistidda, C; Milanese, Chiara; Emmler, T; Karimi, F; Chaudhary, Al; Chierotti, Mr; Klassen, T; Dornheim, M.
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1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/1181070
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