Five-membered aromatic heterocycles are a ubiquitous skeleton of pi-conjugated organic compounds, and their incorporation requires synthetic protocols that are not easily industrially sustainable or scalable. Improved methodologies for their insertion into pi-scaffolds are therefore necessary. We report an efficient and scalable protocol involving a one-pot cross-Aldol direct arylation reaction protocol for the rapid construction of thiophene- and furan-based pi-extended organic materials.
Domino Direct Arylation and Cross-Aldol for Rapid Construction of Extended Polycyclic pi-Scaffolds
NITTI, ANDREA;PASINI, DARIO
2017-01-01
Abstract
Five-membered aromatic heterocycles are a ubiquitous skeleton of pi-conjugated organic compounds, and their incorporation requires synthetic protocols that are not easily industrially sustainable or scalable. Improved methodologies for their insertion into pi-scaffolds are therefore necessary. We report an efficient and scalable protocol involving a one-pot cross-Aldol direct arylation reaction protocol for the rapid construction of thiophene- and furan-based pi-extended organic materials.File in questo prodotto:
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