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Five-membered aromatic heterocycles are a ubiquitous skeleton of pi-conjugated organic compounds, and their incorporation requires synthetic protocols that are not easily industrially sustainable or scalable. Improved methodologies for their insertion into pi-scaffolds are therefore necessary. We report an efficient and scalable protocol involving a one-pot cross-Aldol direct arylation reaction protocol for the rapid construction of thiophene- and furan-based pi-extended organic materials.

Domino Direct Arylation and Cross-Aldol for Rapid Construction of Extended Polycyclic pi-Scaffolds

NITTI, ANDREA;PASINI, DARIO
2017-01-01

Abstract

Five-membered aromatic heterocycles are a ubiquitous skeleton of pi-conjugated organic compounds, and their incorporation requires synthetic protocols that are not easily industrially sustainable or scalable. Improved methodologies for their insertion into pi-scaffolds are therefore necessary. We report an efficient and scalable protocol involving a one-pot cross-Aldol direct arylation reaction protocol for the rapid construction of thiophene- and furan-based pi-extended organic materials.
2017
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
sì
WOS:000405158900003
2-s2.0-85021987719
Esperti anonimi
Inglese
Internazionale
STAMPA
139
26
8788
8791
4
28621529
Catalysis; Chemistry (all); Biochemistry; Colloid and Surface Chemistry
http://pubs.acs.org/journal/jacsat
sì
5
info:eu-repo/semantics/article
262
Nitti, Andrea; Bianchi, Gabriele; Po, Riccardo; Swager, Timothy M.; Pasini, Dario
1 Contributo su Rivista::1.1 Articolo in rivista
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1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/1188823
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