Electron paramagnetic resonance experimental results of potassium tantalate single crystals doped by Co2+ ions as well as new results of our continuous studies of KTaO3:Cu single crystals are presented. Divalent impurity ions substitute for Ta5+ in the octahedron position in the KTO3 crystal and oxygen vacancies are required to compensate the extra charge of Ta5+. The Cu2+ ions associated with oxygen vacancies form only axial centres (included exchange coupled pair centre), the symmetry axes being along cubic directions. A new axial centre of Co2+ in the crystal of KTaO3:Co has been studied
Divalent impurity ions in potassium tantalate crystals: EPR investigations.
BADALYAN, ANDREI;AZZONI, CARLO;GALINETTO, PIETRO;MOZZATI, MARIA CRISTINA;
2005-01-01
Abstract
Electron paramagnetic resonance experimental results of potassium tantalate single crystals doped by Co2+ ions as well as new results of our continuous studies of KTaO3:Cu single crystals are presented. Divalent impurity ions substitute for Ta5+ in the octahedron position in the KTO3 crystal and oxygen vacancies are required to compensate the extra charge of Ta5+. The Cu2+ ions associated with oxygen vacancies form only axial centres (included exchange coupled pair centre), the symmetry axes being along cubic directions. A new axial centre of Co2+ in the crystal of KTaO3:Co has been studiedFile in questo prodotto:
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