Modification of graphene has been undertaken in many research contexts in order to improve its properties. In this study, we examine Ni-nanoparticles decoration on graphene and its effect on sodium-ion battery performance. A definite trend is observed on the relationship between Ni-nanoparticles concentration (and hence size) and battery performance. Comparable capacities on the order of 420 mAhg-1 after 20 cycles at 100 mAg-1 is observed for the 3 relatively high Ni-concentration samples NiC10, NiC40, and NiC80. As the Ni:C ratio decreases, a decreasing trend is observed in the measured capacity, with NiC200, NiC500, and NiC1000 producing capacities of 350 mAhg-1 , 380 mAhg-1 , and 300 mAhg-1 respectively after 20 cycles at the same rate. Ex situ energy dispersive X-ray spectroscopy, scanning, and transmission electron microscopy shows the morphology of the Ni-nanoparticles decorated graphene and assists in quantifing their sodium content, emphasizing the increasing sodium content with increasing Ni-nanoparticles concentration. This systematic study details how Ni-nanoparticles concentration on graphene surfaces can be manipulated to enhance electrochemical performance, and that higher concentrations up to NiC10 favour better performance. For a compromise between performance and cost (Ni cost), the best composition is NiC500 which favors best performance with the least Ni decoration.
Effect of Ni-nanoparticles decoration on graphene to enable high capacity sodium-ion battery negative electrodes
MILANESE, CHIARAInvestigation
;
2017-01-01
Abstract
Modification of graphene has been undertaken in many research contexts in order to improve its properties. In this study, we examine Ni-nanoparticles decoration on graphene and its effect on sodium-ion battery performance. A definite trend is observed on the relationship between Ni-nanoparticles concentration (and hence size) and battery performance. Comparable capacities on the order of 420 mAhg-1 after 20 cycles at 100 mAg-1 is observed for the 3 relatively high Ni-concentration samples NiC10, NiC40, and NiC80. As the Ni:C ratio decreases, a decreasing trend is observed in the measured capacity, with NiC200, NiC500, and NiC1000 producing capacities of 350 mAhg-1 , 380 mAhg-1 , and 300 mAhg-1 respectively after 20 cycles at the same rate. Ex situ energy dispersive X-ray spectroscopy, scanning, and transmission electron microscopy shows the morphology of the Ni-nanoparticles decorated graphene and assists in quantifing their sodium content, emphasizing the increasing sodium content with increasing Ni-nanoparticles concentration. This systematic study details how Ni-nanoparticles concentration on graphene surfaces can be manipulated to enhance electrochemical performance, and that higher concentrations up to NiC10 favour better performance. For a compromise between performance and cost (Ni cost), the best composition is NiC500 which favors best performance with the least Ni decoration.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.