We have developed the first catalytic asymmetric aldehyde allylation by Umpolung of a p-allyl palladium complex mediated by diethylzinc, which afforded products in satisfactory yields with ee values up to 70 %.
Enantioselective catalytic alkylation of carbonyl groups by umpolung of p-allyl palladium complexes
ZANONI, GIUSEPPE;MARCHETTI, ALBERTO;VIDARI, GIOVANNI
2004-01-01
Abstract
We have developed the first catalytic asymmetric aldehyde allylation by Umpolung of a p-allyl palladium complex mediated by diethylzinc, which afforded products in satisfactory yields with ee values up to 70 %.File in questo prodotto:
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