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C–H alkylations of purine nucleosides were achieved by means of user-friendly nickel catalysis with ample substrate scope and high levels of chemo, site and regio control, which among others enabled the direct fluorescent labeling of purines in terms of late stage diversification.

Nickel-catalyzed C-H activation of purine bases with alkyl halides

Ghorai, Debasish;Zanoni, Giuseppe
Conceptualization
;Ackermann, Lutz
Project Administration
2017-01-01

Abstract

C–H alkylations of purine nucleosides were achieved by means of user-friendly nickel catalysis with ample substrate scope and high levels of chemo, site and regio control, which among others enabled the direct fluorescent labeling of purines in terms of late stage diversification.
2017
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
CHEMICAL COMMUNICATIONS
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WOS:000407333400017
2-s2.0-85027419488
Esperti anonimi
Inglese
Internazionale
STAMPA
53
65
9113
9116
4
28759075
Catalysis; Electronic, Optical and Magnetic Materials; Ceramics and Composites; Chemistry (all); Surfaces, Coatings and Films; 2506; Materials Chemistry2506 Metals and Alloys
www.rsc.org/chemcomm
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4
info:eu-repo/semantics/article
262
Ruan, Zhixiong; Ghorai, Debasish; Zanoni, Giuseppe; Ackermann, Lutz
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/1211123
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