The generation of alkoxy radicals from N-alkoxyazinium or azolium salts, occurring via the facile mono-electronic photocatalytic reduction of the starting compounds, has been recently reported. The photogenerated radicals can be in turn exploited for synthetic applications. These include the possibility to promote inter- or intramolecular hydrogen atom transfer processes to generate P- or C-centered radicals, and the direct addition onto unsaturated derivatives for the construction of C–O bonds.
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Titolo: | Alkoxy radicals generation: facile photocatalytic reduction of N-alkoxyazinium or azolium salts |
Autori: | RAVELLI, DAVIDE (Corresponding) |
Data di pubblicazione: | 2019 |
Rivista: | |
Abstract: | The generation of alkoxy radicals from N-alkoxyazinium or azolium salts, occurring via the facile mono-electronic photocatalytic reduction of the starting compounds, has been recently reported. The photogenerated radicals can be in turn exploited for synthetic applications. These include the possibility to promote inter- or intramolecular hydrogen atom transfer processes to generate P- or C-centered radicals, and the direct addition onto unsaturated derivatives for the construction of C–O bonds. |
Handle: | http://hdl.handle.net/11571/1278486 |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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