In this paper we describe the synthesis and intercomparison of several new methanofullerenes, each bearing a macrocyclic crown ether containing a malonate moiety directly attached to the C-60-fullerene core. Their complexing abilities with primary alkylammonium ions were investigated by NMR and mass spectrometry, and also by transport experiments through a liquid membrane. We also report on their electrochemical behaviour, together with EPR analysis of their supramolecular complexes with alkyl ammonium molecules labelled with a stable nitroxide radical.
Methanofullerenes from Macrocyclic Malonates
GARLASCHELLI, LUIGI;PASINI, DARIO;RIGHETTI, PIER PAOLO;
2003-01-01
Abstract
In this paper we describe the synthesis and intercomparison of several new methanofullerenes, each bearing a macrocyclic crown ether containing a malonate moiety directly attached to the C-60-fullerene core. Their complexing abilities with primary alkylammonium ions were investigated by NMR and mass spectrometry, and also by transport experiments through a liquid membrane. We also report on their electrochemical behaviour, together with EPR analysis of their supramolecular complexes with alkyl ammonium molecules labelled with a stable nitroxide radical.File in questo prodotto:
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