A new macrocyclic ligand, whose dicopper complex acts as a receptor for dianions in water at physiological pH, was prepared, and comparison with a structurally isomeric but larger complex demonstrates that the selectivity pattern for dicarboxylate binding obeys the principles of preorganization and linear recognition.
Linear Recognition of Dicarboxylates by Ditopic Macrocyclic Complexes
BOIOCCHI, MASSIMO;BONIZZONI, MARCO;PASINI, DARIO;TAGLIETTI, ANGELO MARIA
2007-01-01
Abstract
A new macrocyclic ligand, whose dicopper complex acts as a receptor for dianions in water at physiological pH, was prepared, and comparison with a structurally isomeric but larger complex demonstrates that the selectivity pattern for dicarboxylate binding obeys the principles of preorganization and linear recognition.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
