The mononuclear complex [Cu(L)]+ performs the orthooxygenation of an exogeneous phenol through the formation of a dinuclear m-h2+h2-peroxodicopper(II) intermediate, which is so far the only type of copper–dioxygen complex that mediates the tyrosinase monophenolase reaction
The phenol ortho-oxygenation by mononuclear copper(I) complexes requires a dinuclear mu-eta2:eta2-peroxodicopper(II) complex rather than mononuclear CuO2 species”
MONZANI, ENRICO;CASELLA, LUIGI
2003-01-01
Abstract
The mononuclear complex [Cu(L)]+ performs the orthooxygenation of an exogeneous phenol through the formation of a dinuclear m-h2+h2-peroxodicopper(II) intermediate, which is so far the only type of copper–dioxygen complex that mediates the tyrosinase monophenolase reactionFile in questo prodotto:
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