Optical Evidence for Symmetry Changes above the Néel Temperature of KCuF3

We report on optical measurements of the 1D Heisenberg antiferromagnet KCuF(3). The crystal-field excitations of the Cu(2+) ions have been observed and their temperature dependence can be understood in terms of magnetic and exchange-induced dipole mechanisms and vibronic interactions. Above T(N) we observe a new temperature scale T(S) characterized by the emergence of narrow absorption features that correlate with changes of the orbital ordering as observed by Paolasini et al. [Phys. Rev. Lett. 88, 106403 (2002)]. The appearance of these optical transitions provides evidence for a symmetry change above the Neel temperature that affects the orbital ordering and paves the way for the antiferromagnetic ordering.