A highly enantioselective synthesis of the (8S,12S)-enantiomer of preclavulone A and its methyl ester is described featuring the Julia protocol for installing the (Z)-double bond in the lower chain. This procedure is suitable for the preparation of labeled preclavulone analogues for biosynthetic studies on marine clavulones.
Enantioselective synthesis of preclavulone A and its methyl ester
PORTA, ALESSIOConceptualization
;ZANONI, GIUSEPPEConceptualization
;VIDARI, GIOVANNI
Conceptualization
2007-01-01
Abstract
A highly enantioselective synthesis of the (8S,12S)-enantiomer of preclavulone A and its methyl ester is described featuring the Julia protocol for installing the (Z)-double bond in the lower chain. This procedure is suitable for the preparation of labeled preclavulone analogues for biosynthetic studies on marine clavulones.File in questo prodotto:
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