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In this work, the possibility of creating a polymer-based adaptive scaffold for improving the hydrogen storage properties of the system 2LiH+MgB2+7.5(3TiCl3·AlCl3) was studied. Because of its chemical stability toward the hydrogen storage material, poly(4-methyl-1-pentene) or in-short TPXTM was chosen as the candidate for the scaffolding structure. The composite system was obtained after ball milling of 2LiH+MgB2+7.5(3TiCl3·AlCl3) and a solution of TPXTM in cyclohexane. The investigations carried out over the span of ten hydrogenation/de-hydrogenation cycles indicate that the material containing TPXTM possesses a higher degree of hydrogen storage stability.

Enhanced stability of Li-RHC embedded in an adaptive TPXTM polymer scaffold

Milanese C.
Supervision
;
2020-01-01

Abstract

In this work, the possibility of creating a polymer-based adaptive scaffold for improving the hydrogen storage properties of the system 2LiH+MgB2+7.5(3TiCl3·AlCl3) was studied. Because of its chemical stability toward the hydrogen storage material, poly(4-methyl-1-pentene) or in-short TPXTM was chosen as the candidate for the scaffolding structure. The composite system was obtained after ball milling of 2LiH+MgB2+7.5(3TiCl3·AlCl3) and a solution of TPXTM in cyclohexane. The investigations carried out over the span of ten hydrogenation/de-hydrogenation cycles indicate that the material containing TPXTM possesses a higher degree of hydrogen storage stability.
2020
Applied Physics/Condensed Matter/Materials Science encompasses the resources of three related disciplines: Applied Physics, Condensed Matter Physics, and Materials Science. The applied physics resources are concerned with the applications of topics in condensed matter as well as optics, vacuum science, lasers, electronics, cryogenics, magnets and magnetism, acoustical physics and mechanics. The condensed matter physics resources are concerned with the study of the structure and the thermal, mechanical, electrical, magnetic and optical properties of condensed matter. They include superconductivity, surfaces, interfaces, thin films, dielectrics, ferroelectrics and semiconductors. The materials science resources are concerned with the physics and chemistry of materials and include ceramics, composites, alloys, metals and metallurgy, nanotechnology, nuclear materials, adhesion and adhesives. Resources dealing with polymeric materials are listed in the Organic Chemistry/Polymer Science category.
The Physical Chemistry/Chemical Physics category includes resources on photochemistry, solid state chemistry, kinetics, catalysis, quantum chemistry, surface chemistry, electro-chemistry, chemical thermodynamics, thermo-physics, colloids, fullerenes and zeolites. Resources dealing with (liquid) crystals and crystallography are also included in this category. This category also includes resources on atomic, molecular and chemical physics, which concerns the structure of atoms and molecules, atomic and molecular interactions with radiation, magnetic resonance and relaxation, Mossbauer effect, and atomic and molecular collision processes and interactions.
MATERIALS
WOS:000520419300182
2-s2.0-85082099673
Esperti anonimi
Inglese
Internazionale
ELETTRONICO
13
4
991
32098426
Carbon-based polymer; Confined complex hydrides; Confinement; Hydrogen storage
sì
11
info:eu-repo/semantics/article
262
Le, T. T.; Pistidda, C.; Abetz, C.; Georgopanos, P.; Garroni, S.; Capurso, G.; Milanese, C.; Puszkiel, J.; Dornheimm, M.; Abetz, V.; Klassen, T....espandi
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/1364554
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