Tactoids are pointed, spindlelike droplets of nematic liquid crystal in an isotropic fluid. They have long been observed in inorganic and organic nematics, in thermotropic phases as well as lyotropic colloidal aggregates. The variational problem of determining the optimal shape of a nematic droplet is formidable and has only been attacked in selected classes of shapes and director fields. Here, by considering a special class of admissible solutions for a bipolar droplet, we study the prevalence in the population of all equilibrium shapes of each of the three that may be optimal (tactoids primarily among them). We show how the prevalence of a shape is affected by a dimensionless measure α of the drop’s volume and the ratios k24 and k3 of the saddle-splay constant K24 and the bending constant K33 of the material to the splay constant K11. Tactoids, in particular, prevail for α < 16.2 + 0.3k3 − (14.9 − 0.1k3 )k24 . Our class of shapes (and director fields) is sufficiently different from those employed so far to unveil a rather different role of K24.

Nematic tactoid population

Paparini, Silvia;Virga, Epifanio G.
2021-01-01

Abstract

Tactoids are pointed, spindlelike droplets of nematic liquid crystal in an isotropic fluid. They have long been observed in inorganic and organic nematics, in thermotropic phases as well as lyotropic colloidal aggregates. The variational problem of determining the optimal shape of a nematic droplet is formidable and has only been attacked in selected classes of shapes and director fields. Here, by considering a special class of admissible solutions for a bipolar droplet, we study the prevalence in the population of all equilibrium shapes of each of the three that may be optimal (tactoids primarily among them). We show how the prevalence of a shape is affected by a dimensionless measure α of the drop’s volume and the ratios k24 and k3 of the saddle-splay constant K24 and the bending constant K33 of the material to the splay constant K11. Tactoids, in particular, prevail for α < 16.2 + 0.3k3 − (14.9 − 0.1k3 )k24 . Our class of shapes (and director fields) is sufficiently different from those employed so far to unveil a rather different role of K24.
2021
The Mathematics category includes resources dealing with mathematics, applied mathematics, statistics and probability.
Esperti anonimi
Inglese
Internazionale
STAMPA
103
2
022707
18
Nematic liquid crystals, Solutions
no
2
info:eu-repo/semantics/article
262
Paparini, Silvia; Virga, Epifanio G.
1 Contributo su Rivista::1.1 Articolo in rivista
none
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/1390374
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