The structure/property relationship of the following CT salts, [M(R2pipdt)2][M(mnt)2] (where R2pipdt = N,N'-dialkylpiperazine-2,3-dithione; mnt = maleonitrile-2,3-dithiolate), [R = Me, M = Pd and Pt ; R = Et, M = Pt ], which were previously characterised, and [Pt(R2pipdt)2][Pt(dtcr)2] [R = Me, Et; dtcr = 4,5-disulfanylcyclopent-4-ene-1,2,3-trionate, known as dithiocroconate] are investigated here. These salts show strong near IR CT bands and semiconducting behaviour.
Electro-Conducting Properties of Charge-Transfer Salts based on Cationic and Anionic Platinum Dithiolenes
SANNA, SAMUELE
2005-01-01
Abstract
The structure/property relationship of the following CT salts, [M(R2pipdt)2][M(mnt)2] (where R2pipdt = N,N'-dialkylpiperazine-2,3-dithione; mnt = maleonitrile-2,3-dithiolate), [R = Me, M = Pd and Pt ; R = Et, M = Pt ], which were previously characterised, and [Pt(R2pipdt)2][Pt(dtcr)2] [R = Me, Et; dtcr = 4,5-disulfanylcyclopent-4-ene-1,2,3-trionate, known as dithiocroconate] are investigated here. These salts show strong near IR CT bands and semiconducting behaviour.File in questo prodotto:
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