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Arylated cyclobutanes were accessed by a versatile palladium-catalyzed secondary C(sp3)−H activation, exploiting chelation assistance by modular triazoles. The C−H arylation led to cyclobutane natural product derivatives in a highly regioselective fashion, setting the stage for the easy access to novel fluorogenic boron-dipyrrin (BODIPY)-labeled probes for live-cell imaging.

BODIPY-Labeled Cyclobutanes by Secondary C(sp3)−H Arylations for Live-Cell Imaging

Virelli M.;Zanoni G.
;Ackermann L.
2019-01-01

Abstract

Arylated cyclobutanes were accessed by a versatile palladium-catalyzed secondary C(sp3)−H activation, exploiting chelation assistance by modular triazoles. The C−H arylation led to cyclobutane natural product derivatives in a highly regioselective fashion, setting the stage for the easy access to novel fluorogenic boron-dipyrrin (BODIPY)-labeled probes for live-cell imaging.
2019
CHEMISTRY-A EUROPEAN JOURNAL
2-s2.0-85072790825
Inglese
25
55
12712
12718
7
31433877
BODIPY; C(sp; 3; )−H activation; cyclobutanes; labeling; triazoles; Boron; Boron Compounds; Catalysis; Cell Tracking; Chelating Agents; Cyclobutanes; Molecular Structure; Optical Imaging; Palladium; Triazoles
9
info:eu-repo/semantics/article
262
Virelli, M.; Wang, W.; Kuniyil, R.; Wu, J.; Zanoni, G.; Fernandez, A.; Scott, J.; Vendrell, M.; Ackermann, L.
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/1447224
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