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EnglishThe N-benzoylamino-2-cyclopenten-1-ol, derived from the nitrosocarbonyl hetero Diels-Alder cycloaddition reaction followed by the mild reductive N-O bond cleavage, allows for the preparation of cyclopentenyl-nucleoside analogues through the palladium(0)-catalyzed addition of both purine and pyrimidine heterobases to the allylic acetate derivative with retention of the starting material stereochemistry. A systematic study is performed on different heterobases to test the general application of the protocol.
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| Titolo: | Palladium(0)-catalyzed syntheses of cyclopentenyl-nucleoside analogues |
| Autori: | |
| Data di pubblicazione: | 2009 |
| Rivista: | |
| Abstract: | The N-benzoylamino-2-cyclopenten-1-ol, derived from the nitrosocarbonyl hetero Diels-Alder cycloaddition reaction followed by the mild reductive N-O bond cleavage, allows for the preparation of cyclopentenyl-nucleoside analogues through the palladium(0)-catalyzed addition of both purine and pyrimidine heterobases to the allylic acetate derivative with retention of the starting material stereochemistry. A systematic study is performed on different heterobases to test the general application of the protocol. |
| Handle: | http://hdl.handle.net/11571/144745 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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