n their paper “Entropy-Stabilized Oxides,” Rost et al. reported the synthesis of a new Mg0.2Co0.2Ni0.2Cu0.2Zn0.2O phase (E1) with rock-salt structure as a test case for the concept of high entropy in oxides. Their claim is that “entropy predominates the thermodynamic landscape and drives a reversible solid-state transformation between a multiphase and single-phase state.” Here we use the same thermodynamic considerations by Rost et al. and replicate their experiments but reducing appropriately the configurational entropy. We demonstrate that configurational entropy does not dominate the thermodynamic stability of E1.
Is configurational entropy the main stabilizing term in rock-salt Mg0.2Co0.2Ni0.2Cu0.2Zn0.2O high entropy oxide?
Fracchia, Martina;Coduri, Mauro;Ghigna, Paolo
;Tamburini, Umberto Anselmi
2022-01-01
Abstract
n their paper “Entropy-Stabilized Oxides,” Rost et al. reported the synthesis of a new Mg0.2Co0.2Ni0.2Cu0.2Zn0.2O phase (E1) with rock-salt structure as a test case for the concept of high entropy in oxides. Their claim is that “entropy predominates the thermodynamic landscape and drives a reversible solid-state transformation between a multiphase and single-phase state.” Here we use the same thermodynamic considerations by Rost et al. and replicate their experiments but reducing appropriately the configurational entropy. We demonstrate that configurational entropy does not dominate the thermodynamic stability of E1.File in questo prodotto:
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