A combined experimental and computational investigation of the photoreactivity of (E)-beta-nitroenones pointed out the occurrence of competitive pathways namely stereoisomerisation to (E)-beta-nitroenones and deconjugation to beta-nitro-beta,gamma-enones. Both processes are generated from the triplet excited state of the starting substrates.
Visible-Light-Driven Competitive Stereo- and Regioisomerization of (E)-beta-Nitroenones
Raviola, C;Serra, M;Palmieri, A;Protti, S
2021-01-01
Abstract
A combined experimental and computational investigation of the photoreactivity of (E)-beta-nitroenones pointed out the occurrence of competitive pathways namely stereoisomerisation to (E)-beta-nitroenones and deconjugation to beta-nitro-beta,gamma-enones. Both processes are generated from the triplet excited state of the starting substrates.File in questo prodotto:
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