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Insummary, using the readily available [ReOCl3(OPPh3)DMS)] complex we have developed a new general catalytic procedure for the rapid and efficient 1,3-rearrangement of free secondary alcohols to the corresponding alpha-beta usatured carbonyl compounds with virtually complete E stereoselectivity.

A simple and versatile Re-catalyzed Meyer-Schuster rearrangement of propargylic alcohols to α,β-unsaturated carbonyl compounds

LUPARIA, MARCO;PORTA, ALESSIO;ZANONI, GIUSEPPE
Conceptualization
;VIDARI, GIOVANNI
2009-01-01

Abstract

Insummary, using the readily available [ReOCl3(OPPh3)DMS)] complex we have developed a new general catalytic procedure for the rapid and efficient 1,3-rearrangement of free secondary alcohols to the corresponding alpha-beta usatured carbonyl compounds with virtually complete E stereoselectivity.
2009
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
CHEMISTRY-A EUROPEAN JOURNAL
sì
WOS:000265509700003
2-s2.0-65349128751
Esperti anonimi
Inglese
Internazionale
STAMPA
15
3940
3944
5
19283809
Meyer-Schuster; propargylic alcohol; α; β-unsaturated carbonyl compounds
no
5
info:eu-repo/semantics/article
262
Stefanoni, Massimo; Luparia, Marco; Porta, Alessio; Zanoni, Giuseppe; Vidari, Giovanni
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/148380
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