Triptycene-based diiron(II) and dizinc(II) mesocates were obtained using a novel rigid ligand with two pyridylbenzimidazole chelating units fused into the triptycene scaffold. Studies on the diiron(II) assembly in solution showed that the complex undergoes thermal-induced one-step spin-crossover with T1/2 at 243 K (Evans method).
Triptycene-based diiron(ii) mesocates: spin-crossover in solution
Mobili, Riccardo;Preda, Giovanni;Dondi, Daniele;Monzani, Enrico;Vadivel, Dhanalakshmi;Pasini, Dario;Amendola, Valeria
2024-01-01
Abstract
Triptycene-based diiron(II) and dizinc(II) mesocates were obtained using a novel rigid ligand with two pyridylbenzimidazole chelating units fused into the triptycene scaffold. Studies on the diiron(II) assembly in solution showed that the complex undergoes thermal-induced one-step spin-crossover with T1/2 at 243 K (Evans method).File in questo prodotto:
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