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Triptycene-based diiron(II) and dizinc(II) mesocates were obtained using a novel rigid ligand with two pyridylbenzimidazole chelating units fused into the triptycene scaffold. Studies on the diiron(II) assembly in solution showed that the complex undergoes thermal-induced one-step spin-crossover with T1/2 at 243 K (Evans method).

Triptycene-based diiron(ii) mesocates: spin-crossover in solution

Mobili, Riccardo;Preda, Giovanni;Dondi, Daniele;Monzani, Enrico;Vadivel, Dhanalakshmi;Pasini, Dario;Amendola, Valeria
2024-01-01

Abstract

Triptycene-based diiron(II) and dizinc(II) mesocates were obtained using a novel rigid ligand with two pyridylbenzimidazole chelating units fused into the triptycene scaffold. Studies on the diiron(II) assembly in solution showed that the complex undergoes thermal-induced one-step spin-crossover with T1/2 at 243 K (Evans method).
2024
The Chemistry category includes resources that are general in nature and cover a broad spectrum of topics in the chemical sciences. Resources specifically covering analytical chemistry, inorganic and nuclear chemistry, organic chemistry, physical chemistry, and polymer science will be placed in those particular categories. Miscellaneous and applied chemistry resources may be placed in this category when not appropriate for specific subfields in chemistry.
CHEMICAL COMMUNICATIONS
sì
WOS:001214557700001
2-s2.0-85192323610
Esperti anonimi
Inglese
Internazionale
STAMPA
2024
60
5522
5525
4
38695185
Triptycenes, mesocate, self-assembly, diiron complex, spin-crossover
https://pubs.rsc.org/en/content/articlelanding/2024/cc/d4cc00812j#!
no
8
info:eu-repo/semantics/article
262
Mobili, Riccardo; Preda, Giovanni; Dondi, Daniele; Monzani, Enrico; Vadivel, Dhanalakshmi; Massera, Chiara; Pasini, Dario; Amendola, Valeria
1 Contributo su Rivista::1.1 Articolo in rivista
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1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/1496906
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