The selective conversion of both benzylic and aliphatic alcohols to the corresponding carbonyl compounds has been realized under photoelectrochemical conditions mediated by the decatungstate anion. Comparison with chemical oxidant-promoted and electrochemical conditions demonstrated the superior efficiency of the photoelectrochemical manifold, thanks to the mild conditions involved.
Selective Oxidation of Alcohols to Carbonyls Under Decatungstate-Mediated Photoelectrochemical Conditions
Capucciati, Andrea;Baraglia, Luca;Cassera, Elena;Merli, Daniele;Capaldo, Luca;Ravelli, Davide
2024-01-01
Abstract
The selective conversion of both benzylic and aliphatic alcohols to the corresponding carbonyl compounds has been realized under photoelectrochemical conditions mediated by the decatungstate anion. Comparison with chemical oxidant-promoted and electrochemical conditions demonstrated the superior efficiency of the photoelectrochemical manifold, thanks to the mild conditions involved.File in questo prodotto:
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