The selective conversion of both benzylic and aliphatic alcohols to the corresponding carbonyl compounds has been realized under photoelectrochemical conditions mediated by the decatungstate anion. Comparison with chemical oxidant-promoted and electrochemical conditions demonstrated the superior efficiency of the photoelectrochemical manifold, thanks to the mild conditions involved.

Selective Oxidation of Alcohols to Carbonyls Under Decatungstate-Mediated Photoelectrochemical Conditions

Capucciati, Andrea;Baraglia, Luca;Cassera, Elena;Merli, Daniele;Capaldo, Luca;Ravelli, Davide
2024-01-01

Abstract

The selective conversion of both benzylic and aliphatic alcohols to the corresponding carbonyl compounds has been realized under photoelectrochemical conditions mediated by the decatungstate anion. Comparison with chemical oxidant-promoted and electrochemical conditions demonstrated the superior efficiency of the photoelectrochemical manifold, thanks to the mild conditions involved.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/1514856
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