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The selective conversion of both benzylic and aliphatic alcohols to the corresponding carbonyl compounds has been realized under photoelectrochemical conditions mediated by the decatungstate anion. Comparison with chemical oxidant-promoted and electrochemical conditions demonstrated the superior efficiency of the photoelectrochemical manifold, thanks to the mild conditions involved.

Selective Oxidation of Alcohols to Carbonyls Under Decatungstate-Mediated Photoelectrochemical Conditions

Capucciati, Andrea;Baraglia, Luca;Cassera, Elena;Merli, Daniele;Capaldo, Luca;Ravelli, Davide
2024-01-01

Abstract

The selective conversion of both benzylic and aliphatic alcohols to the corresponding carbonyl compounds has been realized under photoelectrochemical conditions mediated by the decatungstate anion. Comparison with chemical oxidant-promoted and electrochemical conditions demonstrated the superior efficiency of the photoelectrochemical manifold, thanks to the mild conditions involved.
2024
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
CHEMISTRY-A EUROPEAN JOURNAL
sì
WOS:001357333400001
2-s2.0-85208015418
Esperti anonimi
Inglese
Internazionale
STAMPA
30
65
e202402986
8
Alcohols; Carbonyls; Decatungstate anion; Oxidation; Photoelectrochemistry
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202402986
no
6
info:eu-repo/semantics/article
262
Capucciati, Andrea; Baraglia, Luca; Cassera, Elena; Merli, Daniele; Capaldo, Luca; Ravelli, Davide
1 Contributo su Rivista::1.1 Articolo in rivista
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1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/1514856
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