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A graphitic carbon nitride/lead-free double perovskite heterojunction (g-C3N4/Cs2AgBiCl6) has been adopted as a heterogeneous photocatalyst under visible light irradiation. The employed material enabled the atom transfer radical addition-type carbohalogenation of multiple C–C bonds, including (internal) alkenes and alkynes, with alkyl halides. The protocol showed a remarkable functional group tolerance, compatible with the late-stage functionalization of natural and pharmaceutical derivatives, and could be easily scaled up, delivering >1 g of the desired products.

Application of Lead-Free Metal Halide Perovskite Heterojunctions for the Carbohalogenation of C-C Multiple Bonds

Camilla Callegari;Costanza Tedesco;Alessia Corbo;Lorenzo Malavasi
;Davide Ravelli
2025-01-01

Abstract

A graphitic carbon nitride/lead-free double perovskite heterojunction (g-C3N4/Cs2AgBiCl6) has been adopted as a heterogeneous photocatalyst under visible light irradiation. The employed material enabled the atom transfer radical addition-type carbohalogenation of multiple C–C bonds, including (internal) alkenes and alkynes, with alkyl halides. The protocol showed a remarkable functional group tolerance, compatible with the late-stage functionalization of natural and pharmaceutical derivatives, and could be easily scaled up, delivering >1 g of the desired products.
2025
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
ORGANIC LETTERS
sì
WOS:001458423200001
2-s2.0-105001736009
Esperti anonimi
Inglese
Internazionale
STAMPA
27
14
3667
3672
6
40169388
Alkyls, Halogens, Heterojunctions, Hydrocarbons, Inorganic compounds
https://pubs.acs.org/doi/10.1021/acs.orglett.5c00780
no
6
info:eu-repo/semantics/article
262
Callegari, Camilla; Tedesco, Costanza; Corbo, Alessia; Prato, Mirko; Malavasi, Lorenzo; Ravelli, Davide
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/1539657
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