We study the phonon-induced relaxation dynamics in the heterometallic Cr7Ni ring. By assuming that spin-phonon coupling occurs through the modulation of local crystal fields, we investigate the decay of time correlations of molecular observables, such as fluctuations of the cluster magnetization. Single-crystal 1H nuclear magnetic resonance measurements have been performed for two orthogonal orientations of the applied magnetic field. The nuclear spin-lattice relaxation rate 1/T1 probes fluctuations of specific molecular observables, thus allowing to determine the magnetoelastic coupling strength and to calculate the magnetization relaxation time as well as phonon-induced level lifetimes. The knowledge of these time scales is crucial to control the spin dynamics of the magnetic cluster in view of the potential technological applications.
Phonon-induced relaxation in the Cr7Ni magnetic molecule probed by NMR
LASCIALFARI, ALESSANDRO;Lascialfari A
2010-01-01
Abstract
We study the phonon-induced relaxation dynamics in the heterometallic Cr7Ni ring. By assuming that spin-phonon coupling occurs through the modulation of local crystal fields, we investigate the decay of time correlations of molecular observables, such as fluctuations of the cluster magnetization. Single-crystal 1H nuclear magnetic resonance measurements have been performed for two orthogonal orientations of the applied magnetic field. The nuclear spin-lattice relaxation rate 1/T1 probes fluctuations of specific molecular observables, thus allowing to determine the magnetoelastic coupling strength and to calculate the magnetization relaxation time as well as phonon-induced level lifetimes. The knowledge of these time scales is crucial to control the spin dynamics of the magnetic cluster in view of the potential technological applications.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
