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The irradiation of a series of phenyl sulfonates and phosphates leads to the quantitative release of acidity with a reasonable quantum yield (ª0.2). Products characterization, ion chromatography analysis and potentiometric titration are consistent with the intervening of two different paths in this reaction, viz. cationic with phosphates and (mainly) radical with sulfonates.

Cationic and Radical Intermediates in the Acid Photorelease from Aryl Sulfonates and Phosphates

MERLI, DANIELE;PROTTI, STEFANO;FAGNONI, MAURIZIO;ALBINI, ANGELO
2011-01-01

Abstract

The irradiation of a series of phenyl sulfonates and phosphates leads to the quantitative release of acidity with a reasonable quantum yield (ª0.2). Products characterization, ion chromatography analysis and potentiometric titration are consistent with the intervening of two different paths in this reaction, viz. cationic with phosphates and (mainly) radical with sulfonates.
2011
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
sì
WOS:000285749200017
2-s2.0-78650758061
Esperti anonimi
Inglese
Internazionale
ELETTRONICO
10
123
127
5
aryl sulphonates; aryl phosphates; photoacid generator; aryl cation; radical
no
6
info:eu-repo/semantics/article
262
Terpolilli, M; Merli, Daniele; Protti, Stefano; Dichiarante, V; Fagnoni, Maurizio; Albini, Angelo
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/223506
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