IRIS

A simple and convenient synthesis of a-ionone, an important component of flowers and fragrances. The key step in the formation of the a,b-unsaturated ketone moiety involves an NHC-AuI cat- alyzed Meyer–Schuster-like rearrangement of readily prepared propargylic esters.

Gold-mediated Synthesis of α-ionone

MERLINI, VALENTINA;PORTA, ALESSIO;ZANONI, GIUSEPPE;VIDARI, GIOVANNI;
2011-01-01

Abstract

A simple and convenient synthesis of a-ionone, an important component of flowers and fragrances. The key step in the formation of the a,b-unsaturated ketone moiety involves an NHC-AuI cat- alyzed Meyer–Schuster-like rearrangement of readily prepared propargylic esters.
2011
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
TETRAHEDRON LETTERS
sì
WOS:000287778300020
2-s2.0-79551686982
Sì, ma tipo non specificato
Inglese
Internazionale
STAMPA
52
1124
1127
4
Total Sinthesys; Gold-I; fragrances; IONONE
6
info:eu-repo/semantics/article
262
Merlini, Valentina; Gaillard, Sylvain; Porta, Alessio; Zanoni, Giuseppe; Vidari, Giovanni; Nolan Steven, P.
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/225198
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 27
  • ???jsp.display-item.citation.isi??? 26
social impact