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The molecular and crystal structures of 8-benzyl- 5-phenyl-3-oxa-4,8-diaza-tricyclo[5.2.1.02,6]dec-4-ene 11a and 1-(9-ethoxy-5-phenyl-3-oxa-4,8-diaza-tricyclo[5.2.1.02,6] dec-4-en-8-yl)-ethanone 13a have been XRD determined. The compounds crystallize in the monoclinic system with space groups P21/n and P21/c, respectively. The synthesis and chemical relationship between the two compounds are reported and their structures are compared with others of the aza-norbornene and isoxazoline families.

Structure Determination of 8-Benzyl-5-phenyl-3-oxa-4,8-diazatricyclo[5.2.1.02,6]dec-4-ene and 1-(9-Ethoxy-5-phenyl-3-oxa-4,8-diaza-tricyclo[5.2.1.02,6]dec-4-en-8-yl)-ethanone: Their Synthesis, Chemical Relationship and Comparison with Similar Compounds

QUADRELLI, PAOLO;BOVIO, BRUNA;PICCANELLO, ANDREA
2012-01-01

Abstract

The molecular and crystal structures of 8-benzyl- 5-phenyl-3-oxa-4,8-diaza-tricyclo[5.2.1.02,6]dec-4-ene 11a and 1-(9-ethoxy-5-phenyl-3-oxa-4,8-diaza-tricyclo[5.2.1.02,6] dec-4-en-8-yl)-ethanone 13a have been XRD determined. The compounds crystallize in the monoclinic system with space groups P21/n and P21/c, respectively. The synthesis and chemical relationship between the two compounds are reported and their structures are compared with others of the aza-norbornene and isoxazoline families.
2012
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
sì
000301794300009
2-s2.0-84856306095
Sì, ma tipo non specificato
Inglese
Internazionale
STAMPA
42
43
66
24
Isoxazoline derivatives, 2-azanorborn-5-ene, 1,3-dipolar cycloadditions, Crystal structures
no
3
info:eu-repo/semantics/article
262
Quadrelli, Paolo; Bovio, Bruna; Piccanello, Andrea
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/342926
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