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The regiochemistry of the cycloadditions of nitrile oxides to amides has been investigated experimentally and through DFT calculations.

Cycloaddition of nitrile oxides to cyclic and acyclic alpha,beta-unsaturated amides. Frontier orbital interactions and an unexpected steric drift determine regiochemistry

CARAMELLA, PIERLUIGI;QUADRELLI, PAOLO;
1999-01-01

Abstract

The regiochemistry of the cycloadditions of nitrile oxides to amides has been investigated experimentally and through DFT calculations.
1999
Applied Physics/Condensed Matter/Materials Science encompasses the resources of three related disciplines: Applied Physics, Condensed Matter Physics, and Materials Science. The applied physics resources are concerned with the applications of topics in condensed matter as well as optics, vacuum science, lasers, electronics, cryogenics, magnets and magnetism, acoustical physics and mechanics. The condensed matter physics resources are concerned with the study of the structure and the thermal, mechanical, electrical, magnetic and optical properties of condensed matter. They include superconductivity, surfaces, interfaces, thin films, dielectrics, ferroelectrics and semiconductors. The materials science resources are concerned with the physics and chemistry of materials and include ceramics, composites, alloys, metals and metallurgy, nanotechnology, nuclear materials, adhesion and adhesives. Resources dealing with polymeric materials are listed in the Organic Chemistry/Polymer Science category.
TETRAHEDRON
sì
000080579600027
2-s2.0-0033612129
Esperti anonimi
Inglese
Internazionale
STAMPA
55
7027
7044
18
Cycloadditions, 1,3-Dipoles, Amides, Regiochemistry, Steric effect
no
4
info:eu-repo/semantics/article
262
Caramella, Pierluigi; Quadrelli, Paolo; Falzoni, Mario; Reami, Daniela
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/4040
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